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In the title compound, [CoCl 2 (C 10 H 8 N 2 S) 2 ]  n  , the Co II  atom is located on an inversion centre and is six-coordinated by four N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in  trans  positions, in a distorted octa­hedral geometry. The bridging bidentate di-4-pyridyl sulfide ligands link the Co II  centres into a three-dimensional network. The four coordinating pyridine groups are donors and acceptors (N atoms) for intra­molecular C—H⋯N and C—H⋯Cl hydrogen bonds.

Poly[dichloridobis(μ2-di-4-pyridyl sulfide-κ2N,N′)cobalt(II)]

Poly[dichloridobis(μ₂-di-4-pyridyl sulfide-κ²N,N′)cobalt(II)]