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In the title complex, [Ni(C 7 H 4 O 2 S)(C 26 H 24 P 2 )]·CH 3 OH, the nickel(II) centre adopts an approximately square-planar geometry, with the Ni atom coordinating to the S and O atoms of the bidentate thio­salicylate ligand and the two P atoms of the chelating Ph 2 PCH 2 CH 2 PPh 2  ligand. There is hydrogen bonding between the methanol solvent mol­ecule and the carbonyl O atom of the thio­salicylate ligand.

acta crystallographica. section e

[1,2-Bis(diphenylphosphino)ethane-κ2P,P′](2-carboxylatothiophenolato-κ2O,S)nickel(II) methanol solvate