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In the cation of the title compound, [Mn(C 18 H 18 N 2 O 4 )(H 2 O) 2 ]ClO 4 ·0.5C 12 H 24 O 6 ·H 2 O, the Mn III  ion is coordinated by two water O atoms, and two O atoms and two N atoms from the tetradentate 6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]di­phenolate ligand, completing a distorted octa­hedral geometry. One O atom of the 18-crown-6-ether is disordered over two positions with occupancies of 0.70 (2) and 0.30 (2).

acta crystallographica. section e

Diaqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ2O,N,N′,O′}manganese(III) perchlorate 18-crown-6 hemisolvate monohydrate