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The Ni atom in the title compound, [NiCl 2 (C 12 H 10 N 2 O) 2 ]·C 3 H 6 O, adopts a distorted octa­hedral geometry, being ligated by four N atoms from two different phenyl 2-pyridyl ketone oxime ligands and two Cl atoms. In the crystal structure, inter­molecular O—H⋯Cl hydrogen bonds link the mol­ecules into a chain structure along [010]. There is a π–π contact between the pyridine rings [centroid–centroid distance = 3.824 (5) Å].

Dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(II) acetone solvate