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In contrast to the previous refinement from photographic data [Ferrari  et al.  (1955  ▶ ).  Gazz. Chim. Ital.84 , 169–174], the present redetermination of the title compound, caesium hexa­aqua­magnesium arsenate(V), revealed the Cs atom to be on Wyckoff position 4 d  instead of Wyckoff position 4 b  of space group  F3 m . The structure can be derived from the halite structure. The centres of the complex [Mg(OH 2 ) 6 ] octa­hedra and the AsO 4  tetra­hedra (both with3 m  symmetry) are on the respective Na and Cl positions. The building units are connected to each other by O—H⋯O hydrogen bonds. The Cs +  cations (    3 m  symmetry) are located in the voids of this arrangement and exhibit a regular cubocta­hedral 12-coordination to the O atoms of the water mol­ecules. The O atom bonded to As has 2 mm  site symmetry (Wyckoff position 24 f ) and the water-mol­ecule O atom has  m  site symmetry (Wyckoff position 48 h ).

Redetermination of the cubic struvite analogue Cs[Mg(OH2)6](AsO4)

Redetermination of the cubic struvite analogue Cs[Mg(OH₂)₆](AsO₄)