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The asymmetric unit of the title compound, [Fe(C 12 H 6 O 4 )(C 10 H 8 N 2 )], consists of two independent Fe(II) atoms, two naphthalene-1,4-dicarboxyl­ate anions and two 4,4′-bipyridine ligands. The Fe(II) atoms are each coordinated by four O atoms of the naphthalene-1,4-dicarboxyl­ate anions and two N atoms of the 4,4′-bipyridine ligands within a distorted octa­hedron. Two Fe(II) atoms are bridged  via  the carboxyl­ate groups of two symmetry-related anions into dimers, which are further connected into chains. These chains are linked by additional anions into layers that are finally connected by the 4,4′-bipyridine ligands into a three-dimensional coordination network.

Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxylato)iron(II)]