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The title compound, K + ·C 8 H 13 BF 3 O 2− ·H 2 O, which was obtained from the reaction of a modified form of  Z -vinylic telluride  via  a transmetalation reaction with  n -BuLi, crystallizes as K +  and C 8 H 13 BF 3 O 2−  ions along with a water mol­ecule. The K +  cation is surrounded by four anions, making close contacts with six F atoms at 2.659 (3)–2.906 (3) Å and with two O atoms at 2.806 (3) and 2.921 (3) Å in a distorted bicapped trigonal-prismatic geometry.

Potassium trifluoro[(Z)-3-(oxan-2-yloxy)prop-1-en-1-yl]borate monohydrate