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In the cyrstal structure of the title compound, [Cu(NCS)(C 18 H 20 N 2 O 2 )]  n  , the Cu I  atom is coordinated in a distorted tetra­hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio­cyanate anions. The thio­cyanate anion bridges the Cu I  atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an  E , E  configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.

catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2N:S]

catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ²N:S]