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The title compound, [Cu 2 (CF 3 SO 3 ) 2 (C 3 H 9 PS 3 ) 2 ]  n  , crystallizes as infinite chains in which two trimethyl trithio­phosphite ligands and two trifluoro­methane­sulfonate anions bridge the essentially tetra­hedrally coordinated Cu I  ions in an alternating fashion. The P and one S atom of each trimethyl trithio­phosphite ligand are employed for coordination. The mol­ecular structure exhibits the rare motif of copper(I) bridged by two trifluoro­methane­sulfonate anions generating eight-membered rings.

acta crystallographica. section e

catena-Poly[copper(I)-bis(μ-trifluoromethanesulfonato-κ2O:O′)-copper(I)-bis(μ-trimethyl trithiophosphite)-κ2P:S;κ2S:P]