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The nitrilo­triacetate trianion in the title compound, [Zn 2 (C 6 H 6 NO 6 )(C 12 H 8 N 2 ) 3 ]NO 3 ·6H 2 O, is engaged in  N , O , O ′, O "-chelation to the phenanthroline-chelated Zn II  unit, giving a distorted octa­hedral geometry for the metal atom. One of the three O atoms of the trianion that is engaged in chelation also binds to the bis­(phenanthroline)-chelated Zn II  unit, whose five-coordinate geometry is distorted owing to a long Zn⋯O inter­action [2.401 (2) Å]. The dinuclear cations, nitrate anions and uncoordinated water mol­ecules are linked into a three-dimensional network  via  O—H⋯O hydrogen bonds between water molecules and carboxylate O atoms.

μ-Nitrilotriacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexahydrate