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In the title compound, [CdCl 2 (C 18 H 14 N 4 ) 2 ]·0.5H 2 O, the Cd atom assumes a distorted octa­hedral  trans -CdCl 2 N 4  geometry arising from its coordination by two  N , N ′-bidentate 10,11,12,13-tetra­hydro-4,5,9,14-tetra­azabenzo[ b ]triphenyl­ene (TBBT) mol­ecules and two chloride ions. In the crystal, π–π aromatic stacking inter­actions between adjacent TTBT rings are seen, with a centroid–centroid distance of 3.604 (3) Å. An O—H⋯Cl hydrogen bond between the half-occupied water molecule and one chloride ion also occurs.

Dichlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene)cadmium(II) hemihydrate