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The structure of the title compound, C 15 H 21 N 3 O 6 ·H 2 O, is of inter­est with respect to assumed anti­cancer activity. The title mol­ecules are linked through inter­molecular O—H⋯O hydrogen-bonded chains along the  a  axis. These chains are connected by inter­molecular N—H⋯O hydrogen bonds through the crystallographic screw axis along [010], forming layers, which are stabilized by other N—H⋯O bonds with water O atoms as acceptors and O—H⋯O bonds with water H atoms as donors. The H atoms of the protonated amino cation are also involved in inter­molecular N—H⋯O bonding inter­actions.

(S)-2-[(2R,3S)-2-Ammonio-3-hydroxy-3-(4-nitrophenyl)propanamido]-4-methylpentanoate monohydrate