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In the approximately planar molecule of the title compound, C 11 H 8 N 4 O 4 S, the dihedral angle between the thio­phene and benzene rings is 5.73 (10)°. In the crystal structure, bifurcated inter/intra­molecular N—H⋯(O,O) hydrogen bonds are present. The intermolecular links lead to inversion dimers containing an  R22 (12) graph-set motif.

Thiophene-2-carbaldehyde 2,4-dinitrophenylhydrazone