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In the title compound, C 2 H 10 N 22+ ·2C 9 H 3 Br 4 O 4− ·CH 4 O, the N atoms of the ethane-1,2-diamine mol­ecule are protonated. The crystal structure is stabilized by N—H⋯O hydrogen bonds between the ethane-1,2-diaminium cations and 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)bromo­benzoate anions, and by O—H⋯O and N—H⋯O hydrogen bonds between the methanol solvate and both the cation and the anion. In addition, the crystal structure exhibits a C—Br⋯O halogen bond [3.20 (3) Å] and a Br⋯Br inter­action [3.560 (2) Å].

Ethane-1,2-diaminium 3,4,5,6-tetrabromo-2-(methoxycarbonyl)benzoate methanol solvate