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In the title compound, [Ni(C 7 H 5 O 2 )(C 16 H 36 N 4 )]ClO 4 ·C 7 H 6 O 2 , the Ni atom displays a distorted octa­hedral coordination geometry with four N atoms of the ligand  rac -5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane ( L ) in a folded configuration and two benzoate (bz) O atoms. The [Ni( rac-L )(bz)] +  complex cation, perchlorate anion and benzoic acid mol­ecules engage in hydrogen bonding, with N⋯O distances between 2.970 (3) and 3.123 (3) Å and an O⋯O distance of 2.691 (3) Å.

acta crystallographica. section e

(Benzoato-κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate benzoic acid solvate