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The title compound, C 24 H 56 N 4 P 6  or (  i  Pr 2 N) 2 P–P 4 –P(N  i  Pr 2 ) 2 , adopts a butterfly structure, with planar environments for the N atoms and pyramidal environments for the P atoms. The structure studied has a 15% twin component that is related by a twofold rotation about [100].

2,4-Bis[bis(diisopropylamino)phosphanyl]-1,2,3,4-tetraphosphabicyclo[1.1.0]butane