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In the crystal structure of the title compound, [Co(C 12 H 8 N 2 ) 3 ](BF 4 ) 2 ·CH 3 CN, the mol­ecular packing involves dimers of distorted octahedrally coordinated cations which are held together by one π–π [centroid–centroid = 3.542 (4) Å] and two C—H⋯π inter­actions  [2.573 (4) Å] resulting in a P4AE (Parallel Fourfold Aryl Embrace) motif. The anions are found in aryl boxes formed from the phenanthroline ligands.

Tris(phenanthroline-κ2N,N′)cobalt(II) tetrafluoridoborate acetonitrile solvate

Tris(phenanthroline-κ²N,N′)cobalt(II) tetrafluoridoborate acetonitrile solvate