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The title compound, (C 4 H 12 N) 3 [CuMo 2 S 8 ]·C 3 H 7 NO, was obtained from the self-assembly of tetra­thio­molybdate, tetra­methyl­ammonium nitrate and cuprous sulfide in dimethyl­formamide (DMF). The asymmetric unit contains three (NMe 4 ) +  cations, one [Mo 2 S 8 Cu] 3−  anion and one DMF solvent mol­ecule, and no obvious inter­actions are observed between these species. The trinuclear anion can be viewed as fused [MoS 4 Cu] −  units sharing a copper center. The geometric parameters of the trivalent anion are comparable to those reported for other related salts including isomorphous anions, namely (NEt 4 ) 2 (PPh 4 )[Mo 2 S 8 Cu] ( a ) and (Ph 3 P=N=PPh 3 ) 2 (NEt 4 )[W 2 S 8 Cu]·2CH 3 CN ( b ). However, the Mo—Cu—Mo angle is found to be 160.24 (3)° for the title salt, while this angle is 162.97 (2)° in ( a ) and the W—Cu—W angle is 170.3 (2)° in ( b ), indicating that the largest deviation from linearity is in the title compound.

Tris(tetramethylammonium) tetra-μ2-sulfido-tetrasulfidocopper(I)dimolybdenum(VI)N,N-dimethylformamide solvate

Tris(tetramethylammonium) tetra-μ₂-sulfido-tetrasulfidocopper(I)dimolybdenum(VI)N,N-dimethylformamide solvate