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The title compound, [TiW(C 5 H 5 ) 2 (C 7 H 5 O)Cl(CO) 5 ], consists of two metal centres, with a (tungstenpenta­carbon­yl)oxy­phenyl­carbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclo­penta­dienyl rings undergoes an offset face-to-face π–π inter­action [3.544 (6) Å] with the symmetry-related cyclo­penta­dienyl ring of a neighbouring mol­ecule.

acta crystallographica. section e

Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl](μ-α-oxidobenzylidene-1:2κ2O:C)titanium(IV)tungsten(0)