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In the centrosymmetric and dinuclear title complex, [Mn 2 (C 22 H 22 N 4 O 2 )(ClO 4 ) 2 ], the two Mn atoms are bridged by two phenolate O atoms of the N 4 O 2  macrocycle with an Mn⋯Mn distance of 2.9228 (11) Å. The distorted square–pyramidal N 2 O 3  coordination geometry is completed by an O atom derived from a perchlorate anion.

acta crystallographica. section e

[μ-10,21-Dimethyl-3,6,14,17-tetrazatricyclo[17.3.1.18,12]tetracosa-1(23),2,6,8,10,12 (24),13,17,19,21-decaene-23,24-diolato-κ4N3,N6,O23,O24:κ4N14,N17,O23,O24]bis(perchlorato-κO)dimanganese(II)