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In the title compound, [Cu(CHO 2 )(C 12 H 8 N 2 ) 2 ]CHO 2 ·6H 2 O, the Cu atom is coordinated in a distorted trigonal-bipyramidal fashion by an O atom of the formate ligand and four N atoms of two phenanthroline ligands with Cu—O and Cu—N distances of 2.020 (3) and 1.978 (3)–2.177 (3) Å, respectively. Hydrogen bonding O—H⋯O between water molecules and between water anions as well as π–π inter­actions [centroid–centroid distances between phen rings = 3.38 (7) and 3.40 (5) Å] are responsible for the supra­molecular assembly.

(Formato-κO)bis(1,10-phenanthroline-κ2N,N′)copper(II) formate hexahydrate

(Formato-κO)bis(1,10-phenanthroline-κ²N,N′)copper(II) formate hexahydrate