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The mol­ecule of the title compound, [Cu 2 Mo 2 Br 2 (C 7 H 14 NS 2 ) 2 S 4 ]·2C 3 H 7 OH, comprises one [( i -C 3 H 7 ) 2 NCS 2 ] 2 Mo 2 S 4  unit and two CuBr units held together by six Cu—μ 3 -S bonds, thus forming a cubane-like Mo 2 S 4 Cu 2  core. Intramolecular O—H⋯S hydrogen bonds may stabilize the structure. Two methyl groups of the two independent solvent molecules are disordered over two positions and were refined with occupancies of 0.733 (12) and 0.267 (12).

acta crystallographica. section e

Dibromidobis(N,N-diethyldithiocarbamato-κ2S,S′)tetra-μ3-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate