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In the title compound, [Mn(C 5 H 6 N 3 O) 2 (C 3 H 7 NO)]ClO 4 , the Mn III  atom lies on the inversion centre of the centrosymmetric complex cation and has a distorted octa­hedral coordination geometry, formed by two N atoms and two O atoms from two 1-methyl­imidazole-2-carbaldehyde oximate ligands and two O atoms from two dimethyl­formamide ligands. Perchlorate acts as a counterion to balance the charge. The crystal structure of the title compound is stabilized by C—H⋯O hydrogen-bonding inter­actions.

acta crystallographica. section e

Bis(N,N-dimethylformamide-κO)bis(1-methylimidazole-2-carbaldehyde oximato-κ2N,O)manganese(III) perchlorate