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A new monoclinic polymorph of the title compound, [V(2)(C(10)H(13)N(2)O)(2)O(4)], which is a centrosymmetric dimer, crystallizes in space group P2(1)/c, whereas the previously known polymorph crystallizes in the ortho-rhom-bic space group Pbca [Mokry &amp; Carrano (1993 ▶). Inorg. Chem.32, 6119-6121]. Each V(V) atom is six-coordinated by one oxide group, two N atoms and one O atom from the Schiff base ligand, and by two additional bridging O atoms. The two methyl-ene groups are each disordered over two sites, with occupancy factors of 0.776 (14) and 0.224 (14). In the crystal structure, there are C-H⋯O hydrogen bonds and C-H⋯π inter-actions between the dimers.

A monoclinic polymorph of di-μ-oxido-bis({2-[2-(methylamino)ethyliminomethyl]phenolato-κ3N,N′,O}oxidovanadium(V))

A monoclinic polymorph of di-μ-oxido-bis({2-[2-(methylamino)ethyliminomethyl]phenolato-κ³N,N′,O}oxidovanadium(V))