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The Cu II  atom in the title complex, [Cu(C 18 H 21 N 2 O 2 )(C 2 H 3 O 2 )], is tetra­coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intra­molecular inter­action toward the Cu atom, the Cu—O distance of 2.771 (2) Å being shorter than the van der Waals radii for Cu and O atoms (2.92 Å). Furthermore, there are weak inter­molecular inter­actions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) Å is about 0.4 Å shorter than the van der Waals Cu—O distance in other crystal structures.

(Acetato-κO)(2-{[2-(dimethylamino)ethylimino](phenyl)methyl}-5-methoxyphenolato-κ3N,N′,O1)copper(II)

(Acetato-κO)(2-{[2-(dimethylamino)ethylimino](phenyl)methyl}-5-methoxyphenolato-κ³N,N′,O¹)copper(II)