English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The title compound, [Fe 2 (C 9 H 11 NS 2 ){Fe(C 5 H 5 )(C 17 H 14 P)}(CO) 5 ], was prepared as an aza­dithiol­ato–iron model for the iron-only hydrogenase active site. The Fe 2 S 2  unit exhibits a butterfly conformation and the ferrocenyldiphenyl­phosphine ligand is  trans  to the Fe—Fe bond. The Fe—Fe distance of 2.5160 (8) Å is longer than found in related model structures. Intra­molecular C—H⋯S and inter­molecular C—H⋯O hydrogen bonds are observed.

acta crystallographica. section e

Pentacarbonyl-1κ2C,2κ3C-(ferrocenyldiphenylphosphine-1κP)[μ-2-(4-methylphenyl)-2-azapropane-1,3-dithiolato-1:2κ4S,S′:S,S′]diiron(I)(Fe—Fe)