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In the title compound, [Mo(C 5 H 5 )(CO) 2 (C 3 H 9 P) 2 ]CF 3 SO 3 , the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a  trans  configuration of the basal ligands around the Mo atom. The cyclo­penta­dienyl (Cp) ligand occupies the apical position of the piano-stool configuration. The average Mo—P bond length of the two  trans  PMe 3  ligands is 2.474 (5) Å and the Mo—Cp centroid distance is 2.003 (2) Å.

Dicarbonyl(η5-cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonate

Dicarbonyl(η⁵-cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonate