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In the title complex, [Rh(C 6 H 16 P 2 ) 2 ][RhCl 2 (C 8 H 12 )], the asymmetric unit contains two [Rh(dmpe) 2 ] [dmpe = 1,2-bis­(dimethyl­phosphino)ethane] half-cations, lying on inversion centers, and an [RhCl 2 (cod)] −  (cod = 1,5-cyclo­octa­diene) anion, wherein Rh is coordinated by two chloride ligands and two olefinic π-bonds of the cyclo­octa­diene ligand. The Rh atoms in the cations and anion exhibit square-planar coordination and are separated without any unusual inter­actions.

Bis[1,2-bis(dimethylphosphino)ethane-κ2P,P′]rhodium(I) dichlorido[(1,2,5,6-η)-1,5-cyclooctadiene]rhodium(I)

Bis[1,2-bis(dimethylphosphino)ethane-κ²P,P′]rhodium(I) dichlorido[(1,2,5,6-η)-1,5-cyclooctadiene]rhodium(I)