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The Sn atom of the title compound, [Sn(C 2 H 5 ) 2 (C 12 H 12 BrNO 3 )], is in a distorted SnNC 2 O 2  trigonal–bipyramidal geometry and forms five- and six-membered chelate rings with the tridentate ligand. One C atom of one ethyl group is disordered with site occupancies of 0.61 (3):0.39 (3).

[N-(5-Bromo-2-oxidobenzylidene)-L-valinato-κ3O,N,O′]diethyltin(IV)

[N-(5-Bromo-2-oxidobenzylidene)-L-valinato-κ³O,N,O′]diethyltin(IV)