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BaCo 2 Sn 4 O 11  is isotypic with  R -ferrite, BaTi 2 Fe 4 O 11 . The Co atoms fully occupy trigonal–bipyramidal sites (    ) and are disordered with Sn atoms in octa­hedral sites (.2/ m  symmetry), as represented in the formula BaCoSn 2 (Co 0.34 Sn 0.66 ) 4 O 11 . Ba atoms are situated in a 12-fold coordinated site (symmetry).

R-Ferrite-type barium cobalt stannate, BaCo2Sn4O11

R-Ferrite-type barium cobalt stannate, BaCo₂Sn₄O₁₁