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In the title polymeric complex, [HgBr 2 (C 10 H 14 N 2 )]  n  , each nicotine mol­ecule is bonded to two adjacent Hg atoms, one through the pyrrolidine N atom and the other through the pyridine N atom, forming zigzag chains along [010]. The coordination around mercury is completed by two bromido ligands resulting in a distorted tetra­hedral arrangement.

catena-Poly[[dibromidomercury(II)]-μ-3-(1-methylpyrrolidin-2-yl)pyridine-κ2N:N′]

catena-Poly[[dibromidomercury(II)]-μ-3-(1-methylpyrrolidin-2-yl)pyridine-κ²N:N′]