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In the crystal structure of the title salt, [Cr 3 (C 2 H 3 O 2 ) 6 O(H 2 O) 3 ]NO 3 ·CH 3 CO 2 H, the trinuclear [Cr 3 (CH 3 CO 2 ) 6 O(H 2 O) 3 ] cluster cation has an oxide O atom that is connected to three water-coordinated Cr III  atoms, the three metal atoms forming the points of an equilateral triangle. Each of the six acetate carboxyl­ate groups bridges a Cr–O–Cr fragment. The cluster cation inter­acts with the nitrate counter-ion and solvent mol­ecules through O—H⋯O hydrogen bonds, forming a three-dimensional hydrogen-bonded network.

Hexa-μ2-acetato-κ12O:O′-μ3-oxido-tris[aquachromium(III)] nitrate acetic acid solvate

Hexa-μ₂-acetato-κ¹²O:O′-μ₃-oxido-tris[aquachromium(III)] nitrate acetic acid solvate