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In the crystal structure of the title compound, [Co(C 13 H 9 N 2 O) 2 ]·2C 3 H 7 NO, the Co II  ion is four-coordinated by two N atoms and two O atoms from two deprotonated 2-(1 H -benzimidazol-2-yl)phenol ligands in a distorted tetra­hedral geometry. The dimethyl­formamide solvent mol­ecules are found inside a two-dimensional network structure formed by inter­molecular N—H⋯O hydrogen bonds linking the mol­ecules.

Bis[2-(1H-benzimidazol-2-yl)phenolato-κ2N3,O]cobalt(II) dimethylformamide disolvate

Bis[2-(1H-benzimidazol-2-yl)phenolato-κ²N³,O]cobalt(II) dimethylformamide disolvate