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In the title mol­ecule, C 11 H 16 N 2 O 22+ ·2Cl − ·0.5H 2 O, all N atoms are protonated. In the crystal structure, the organic cation and Cl −  ions are linked by N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming a one-dimensional infinite ribbon extending parallel to the (110) plane.

(1S,2S)-2-Carboxy-1-(3-pyridiniomethyl)pyrrolidin-1-ium dichloride hemihydrate