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In the title compound, C 16 H 18 N 2 O 8 S, derived from ranelic acid, there is a highly substituted thio­phene ring. The crystal structure involves inter­molecular C—H⋯O and C—H⋯S hydrogen bonds.

Methyl 5-[N,N-bis(methoxycarbonylmethyl)amino]-4-cyano-2-methoxycarbonyl-3-thiopheneethanoate