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The title compound, [ZrW(C 5 H 5 ) 2 (C 2 H 3 O)Cl(CO) 5 ] or [W(CO) 5 C(CH 3 )OZr(C 5 H 5 ) 2 Cl], consists of two metal centres, with a (tungsten penta­carbon­yl)oxymethyl­carbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the mol­ecule are related by a crystallographic mirror plane. Delocalization through the Zr—O—C=W unit is indicated by a short Zr—O distance and a nearly linear Zr—O—C angle.

acta crystallographica. section e

Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl][μ2-oxido(methyl)methylene-1:2κ2O:C]tungsten(0)zirconium(IV)