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The asymmetric unit of the title compound, [CdCl 2 (C 12 H 12 N 2 )]  n  , contains one half-mol­ecule; a twofold rotation axis passes through the Cd atom. The Cd II  atom is six-coordinated in a distorted octa­hedral configuration by two N atoms from 2,2′-bipyridine-5,5′-dimethyl and four bridging Cl atoms. The bridging function of the chloro atoms leads to a one-dimensional chain structure. There is a π–π contact between the pyridine rings [centroid–centroid distance = 3.9807 (9) Å].

catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ2N,N′)cadmium(II)]-di-μ-chlorido]

catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ²N,N′)cadmium(II)]-di-μ-chlorido]