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In the title binuclear iron(III) complex, [Fe 2 (C 14 H 10 N 2 O 2 ) 3 ]·4C 4 H 8 O or [Fe 2 (salda) 3 ]·4THF [H 2 salda = 2,2′-(azinidimethyl­ene)diphenolate and THF is tetra­hydro­furan], the ligand possesses a rotationally flexible single N—N bond. Three dinucleating  O , N : N ′, O ′-donor ligands provide three diazine (=N—N=) bridges between the metal ions, yielding a binuclear triple helicate structure with crystallographic  C2  symmetry, the rotation axis bis­ecting one N—N bond.

Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ4 O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate

Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ⁴ O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate