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Safflorite, a naturally occurring cobalt-nickel-iron diarsenide (Co,Ni,Fe)As 2 , possesses the marcasite-type structure, with cations ( M  = Co + Ni + Fe) at site symmetry 2/ m  and As anions at  m . The  M As 6  octa­hedra share two edges, forming chains parallel to  c . The chemical formula for safflorite should be expressed as (Co,Ni,Fe)As 2 , rather than the end-member format CoAs 2 , as its structure stabilization requires the simultaneous inter­action of the electronic states of Co, Ni, and Fe with As 22−  dianions.

Safflorite, (Co,Ni,Fe)As2, isomorphous with marcasite

Safflorite, (Co,Ni,Fe)As₂, isomorphous with marcasite