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In the title compound, {[Zn(2)(C(16)H(4)I(2)O(8))(H(2)O)(4)]·2H(2)O}(n), two crystallographically independent Zn(II) atoms are each located on a twofold rotation axis. Both Zn(II) atoms are in distorted octa-hedral coordination geometries: one is coordinated by six O atoms from four carboxyl-ate groups, while the other is coordinated by two carboxyl-ate groups and four water mol-ecules. The tetra-carboxyl-ate ligand mol-ecules connect the Zn(II) atoms, completing a three-dimensional metal-organic framework. O-H⋯O hydrogen bonds link the metal-organic framework with the uncoord-inated water mol-ecules.

Poly[[tetraaqua(μ6-2,2′-diiodobiphenyl-4,4′,5,5′-tetracarboxylato)dizinc(II)] dihydrate]

Poly[[tetraaqua(μ₆-2,2′-diiodobiphenyl-4,4′,5,5′-tetracarboxylato)dizinc(II)] dihydrate]