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In the cation of the title compound, [AuCl(2)(C(24)H(16)N(2))][AuCl(4)], the Au(III) atom is four-coordinated in a distorted square-planar configuration by two N atoms from a 4,7-diphenyl-1,10-phenanthroline ligand and two terminal Cl atoms. In the anion, the Au(III) atom has a square-planar coordination. In the crystal structure, intra- and inter-molecular C-H⋯Cl hydrogen bonds are found.

Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ2 N,N′)gold(III) tetrachloridoaurate(III)

Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ² N,N′)gold(III) tetrachloridoaurate(III)