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The title compound, C 25 H 18 N 2 O 6 , is a naphthalenophane styled in the manner of Warrener’s alicyclic cyclo­phanes or mol­ecular racks wherein a trimethyl­ene tether is perfectly staggered between the two N atoms such that the central methyl­ene H atoms point toward the naphthalene π-system. The dihedral angle between the mean planes of the two benzene rings is 7.61 (7)°.

acta crystallographica. section e

(2R,3aR,4S,7R,7aS,9R,10aR,11S,14R,14aS)-rel-3a,4,7,7a,10a,11,14,14a-Octahydro-4,14:7,11-diepoxy-2,9-propanonaphtho[1,2-f:5,6-f′]diisoindole-1,3,8,10-tetrone (9CI): a cyclophane derived from naphtho[1,2-c:5,6-c]difuran