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In the title compound, [Co(II)(C(2)H(8)N(2))(3)](3)[Mo(V)(CN)(8)](2)·2H(2)O, N-H⋯N and N-H⋯O hydrogen-bonding inter-actions give rise to a three-dimensional network. In the crystal structure, each Mo polyhedron has a square-anti-prismatic shape, while the Co complexes show distorted octa-hedral geometry with an occupancy of 50%. One of the Co atoms resides on a crystallographic inversion centre.

Tris[tris(ethane-1,2-diamine)cobalt(II)] bis[octacyanidomolybdate(V)] dihydrate