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The title dinuclear platinum compound, [Pt 2 Cl 4 (C 22 H 16 N 4 )(C 2 H 6 S) 2 ], with a long bridging bipyridyl-type ligand, is centrosymmetric and the Pt II  cation shows a slightly distorted square-planar coordination geometry. The Cl ligands are  trans  to each other, with a Cl—Pt—Cl angle of 178.83 (8)°. The pyridine ring forms a dihedral angle of 48.8 (2)° with the planar PtCl 2 SN unit. Within the mol­ecule, the distance between Pt atoms is 20.262 (5) Å and the N⋯N separation between the terminal pyridyl rings is 16.23 (1)Å.

{μ-N,N′-Bis[(E)-4-pyridylmethylidene]naphthalene-1,5-diamine}bis[dichlorido(dimethyl sulfide)platinum(II)]