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Mol­ecules of the title compound, C 12 H 7 NOS, with one half-mol­ecule in the asymmetric unit, are disordered about a crystallographic centre of inversion. Refinement showed that the C=O group is disordered with the S atom and the N atom is disordered over four positions. Adjacent mol­ecules are connected through C—H⋯O hydrogen bonds and π⋯π inter­actions (centroid–centroid distances of 3.635 and 3.858 Å).

5H-1-Benzothiopyrano[2,3-b]pyridin-5-one