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The title complex, [Cu 2 (C 7 H 6 NO 2 ) 2 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ]·2C 7 H 7 NO 2 ·2H 2 O, consists of a dinuclear [Cu 2 (C 7 H 6 NO 2 ) 2 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ] 2+  cation, two Cl −  anions, two 4-amino­benzoic acid mol­ecules and two disordered water mol­ecules (site occupancy factors 0.5). The Cu(II) ion adopts a distorted square-pyramidal geometry formed by two N atoms from the 1,10-phenanthroline ligand and two O atoms of the two 4-amino­benzoic acid ligands and one water O atom. The Cu⋯Cu separation is 3.109 (2) Å. A twofold axis passes through the mid-point of the Cu⋯Cu vector.

A dinuclear copper complex: bis(μ-4-aminobenzoato)bis[aqua(1,10-phenanthroline)copper(II)] dichloride bis(4-aminobenzoic acid) dihydrate