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The crystal structure of the title compound, [Co(C 7 H 6 NO 2 S) 2 (H 2 O) 4 ], is a polymorph of the structure first reported by Du, Zhao & Wang [(2004).  Dalton Trans , pp. 2065–2072]. The asymmetric unit of the title compound contains one half-mol­ecule; the Co II  atom lies on an inversion centre in a distorted octa­hedral geometry coordinated by two N atoms of the pyridine rings of the 4-pyridylthio­acetate anions and four O atoms of water mol­ecules. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules, forming a three-dimensional network.

Monoclinic polymorph oftrans-tetraaquabis[(4-pyridylsulfanyl)acetato-κN]cobalt(II)