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The title compound, [Mn(C 5 H 7 O 2 ) 2 (C 12 H 16 N 3 O 2 ) 2 ], is isostructural with its Ni II -containing analogue [Hao, Mu & Kong (2008  ▶ ).  Acta Cryst.  E 64 , m957]. The asymmetric unit comprises one-half of the mol­ecule and the Mn II  ion is located on an inversion centre. The coordination geometry around the Mn II  ion is slightly distorted octa­hedral, comprised of four O and two N atoms, in which the four O atoms in the equatorial plane come from two pentane-2,4-dionate ligands and the two N atoms in the axial coordination sites from 4,4,5,5-tetra­methyl-2-(4-pyrid­yl)imidazoline-1-oxyl 3-oxide.

acta crystallographica. section e

Bis(pentane-2,4-dionato-κ2O,O′)bis[4,4,5,5-tetramethyl-2-(4-pyridyl)imidazoline-1-oxyl 3-oxide-κN2]manganese(II)