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The title compound, C 17 H 16 N 3 O + ·PF 6− , is a chiral bicyclic 1,2,4-triazolium salt. In the crystal packing, C—H⋯O and C—H⋯F hydrogen bonds and P—F⋯π contacts [4.078 (11)–4.163 (11) Å, involving the triazolium ring] play an important role in enhancing the stability of the crystal structure.

2,5-Diphenyl-2,5,6,8-tetrahydro-1,2,4-triazolo[3,4-c][1,4]oxazin-4-ium hexafluoridophosphate