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The cations and anions of the salt, C 10 H 16 N 42+ ·2I 3− , are linked by N—H⋯I hydrogen bonds and π–π stacking inter­actions(with interplanar distances of 3.575 and 3.528 Å) into a three-dimensional supra­molecular network. The asymmetric unit contains two anions and two half-cations; each cation is centrosymmetric.

3,3′-(Butane-1,4-diyl)diimidazole-1,1′-diium bis(triiodide)